AEROTEX NMA 48%
AEROTEX NMA 48%
AEROTEX NMA 48%, offered as a 48% aqueous solution, is a bifunctional monomer possessing both vinyl and hydroxymethyl groups.
AEROTEX NMA 48% is a useful research chemical.
AEROTEX NMA 48% is a colorless or yellow aqueous solution.
CAS Number: 924-42-5
EC Number: 213-103-2
Molecular Formula: C4H7NO2
Molecular Weight: 101.10400
Synonyms: N-(HYDROXYMETHYL)ACRYLAMIDE, METHYLOLACRYLAMIDE, N-MAN, N-MAN PC, NM-AMD, uraminet80, Rocagil BT, NCI-C60333, N-Methylol, Yuramin T 80, N-(HYDROXYMETHYL)ACRYLAMIDE, N-Methylolacrylamide, 924-42-5, Methylolacrylamide, N-Methylol Acrylamide, N-Methanolacrylamide, Monomethylolacrylamide, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, N-Hydroxymethyl acrylamide, Uramine T 80, N-(hydroxymethyl)prop-2-enamide, N-(Hydroxymethyl)-2-propenamide, Hydroxymethylacrylamide, NCI-C60333, N-MAM, NSC 553, Yuramin T 80, W8W68JL80Q, CHEBI:82492, NSC-553, MFCD00004597, N-Methyloacrylamide, CCRIS 2380, HSDB 4361, NM-AMD, EINECS 213-103-2, BRN 0506646, UNII-W8W68JL80Q, AI3-25447, ROCAGIL BT, EC 213-103-2, N-(hydroxymethyl) acrylamide, SCHEMBL25806, METHYLOLACRYLAMIDE, N-, NSC553, CHEMBL1892361, DTXSID3020885, N-METHYLOLACRYLAMIDE [IARC], AKOS006222324, CS-W013710, NCGC00163845-01, NCGC00163845-02, BS-17859, N-(HYDROXYMETHYL)ACRYLAMIDE [HSDB], FT-0720637, M0574, C19456, E78933, EN300-7474805, A844235, W-100289, Q26840808, N-(Hydroxymethyl)acrylamide 100 microg/mL in Acetonitrile, InChI=1/C4H7NO2/c1-2-4(7)5-3-6/h2,6H,1,3H2,(H,5,7, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide,N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 90456-67-0, 160278-55-7, 176598-18-8, 194091-52-6, 211862-48-5, 211862-50-9, n-(hydroxymethyl)-2-propenamide, N-methanolacrylamide, Monomethylolacrylamide, NCI-C60333, Uramine T 80, Acrylamide, N-(hydroxymethyl)-, Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-Methanolacrylamide, N-Methylolacrylamide, Uramine T 80, Yuramin T 80, Methylolacrylamide, N-(Hydroxymethyl)-2-propenamide, NCI-C60333, N-Methyloacrylamide, NM-AMD, NSC 553, N-MAM, 2-Propenamide, N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl)-, N-(Hydroxymethyl)-2-propenamide, N-Methylolacrylamide, N-Methanolacrylamide, N-(Hydroxymethyl)acrylamide, Monomethylolacrylamide, NMA 60, MH 100 (amide), MH 100, N-MAM P, U-Ramin T 80, Rocagil BT, N-MAM, NSC 553, N-NBM, Cylink NMA, N-Methylol acrylamide, NMA 48, 2-Propenamide,N-(hydroxymethyl)-, Acrylamide, N-(hydroxymethyl), Monomethylolacrylamide, n-(hydroxymethyl)-2-propenamid, n-(hydroxymethyl)-acrylamid, NCI-C60333, NM-AMD, N-Methanolacrylamide, Acrylamide, N-(hydroxymethyl, Monomethylolacrylamide, N-(Hydroxymethyl)acrylamide, N-Methanolacrylamide, N-Methylolacrylamide, Uramine T 80, Yuramin T 80, Methylolacrylamide, N-(Hydroxymethyl)-2 propenamide, NCI-C60333, N-Methyloacrylamide, NM-AMD, NSC 553, N-MAM, N-Methylolacrylamide, Acrylamide, N-(hydroxymethyl)-, N-(Hydroxymethyl) acrylamide, N-(Hydroxymethyl)-2-propenamide, N-Methanolacrylamide, Monomethylolacrylamide NMA, 2-Propenamide, N-(hydroxymethyl)-
AEROTEX NMA 48% appears as a colorless or yellow aqueous solution.
AEROTEX NMA 48% is a secondary carboxamide.
AEROTEX NMA 48% is a bifunctional monomer possessing both vinyl and hydroxymethyl groups.
Thermoplastic polymers can be formed through the copolymerization of NMA with a variety of vinyl monomers via emulsion, solution, or suspension techniques.
The resulting products, having pendant hydroxymethyl groups, are self-crosslinkable under moderate conditions.
This mechanism permits the conversion of thermoplastic backbone polymers to thermoset materials at the point of use without the need for an external crosslinker.
Conversely, the hydroxymethyl group can first be reacted with a substrate like cellulose and subsequently cross-linked by free radical polymerization.
AEROTEX NMA 48% is a white solid
AEROTEX NMA 48% is a secondary carboxamide.
AEROTEX NMA 48% is a colorless or yellow aqueous solution.
AEROTEX NMA 48% appears as a colorless or yellow aqueous solution.
AEROTEX NMA 48% is a chemical compound that belongs to the group of ethylene diamines.
AEROTEX NMA 48% appears as a colorless or yellow aqueous solution.
AEROTEX NMA 48% is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum. AEROTEX NMA 48% is a useful research chemical. AEROTEX NMA 48% is a colorless or yellow aqueous solution. AEROTEX NMA 48% is soluble in water. AEROTEX NMA 48% appears as a colorless or yellow aqueous solution. AEROTEX NMA 48% is a secondary carboxamide. AEROTEX NMA 48% is a white solid AEROTEX NMA 48%, offered as a 48% aqueous solution, is a bifunctional monomer possessing both vinyl and hydroxymethyl groups. Thermoplastic polymers can be formed through the copolymerization of NMA with a variety of vinyl monomers via emulsion, solution, or suspension techniques. The resulting products, having pendant hydroxymethyl groups, are self-crosslinkable under moderate conditions. This mechanism permits the conversion of thermoplastic backbone polymers to thermoset materials at the point of use without the need for an external crosslinker. Conversely, the hydroxymethyl group can first be reacted with a substrate like cellulose and subsequently cross-linked by free radical polymerization. AEROTEX NMA 48%, offered as a 48% aqueous solution, is a bifunctional monomer containing both vinyl and hydroxymethyl groups. AEROTEX NMA-LF is specifically designed to provide effective self-crosslinking performance along with significant reduction of both formaldehyde present in the resulting emulsion polymer and formaldehyde released to the environment during cure. AEROTEX NMA-LF combines the cost effectiveness of AEROTEX NMA with a drastic reduction in total formaldehyde. The active self-crosslinking species of AEROTEX NMA-LF is N-methylolacrylamide (NMA). NMA contains a vinyl group and an N-methylol group. The vinyl group is reactive and allows NMA to be easily incorporated into a variety of polymer structures. Once incorporated into the polymer, the methylol group can be activated to cross-link with itself, with other functional groups in the polymer (such as hydroxyls or amines), or with cellulosic substrates. The bifunctional feature of AEROTEX NMA-LF ultimately results in latex binders which provide important performance properties to the final product, such as wet strength, tear strength, and solvent resistance. AEROTEX NMA-LF Monomer (ROW) by allnex is N-methylolacrylamide based monomer. AEROTEX NMA is specifically designed to provide effective self-crosslinking performance together with a significant reduction in both the formaldehyde present in the resulting emulsion polymer and the formaldehyde released to the environment upon curing. AEROTEX NMA's bifunctional feature results in latex binders which provide important performance properties to the final product such as solvent resistance, wet- and tear strength. AEROTEX NMA-LF Monomer (ROW) is used as binders in papermaking, textiles & non-wovens to a variety of surface coatings and resins for varnishes, films and sizing agents. The shelf life of this product is 240 days. Applications of AEROTEX NMA: AEROTEX NMA 48% has been used as a fluorescence probe for fatty acids in polyvinyl compounds, and as an electrochemical impedance spectroscopy (EIS) substrate. AEROTEX NMA 48% also reacts with acrylamide to form polymers. This reaction is catalyzed by hydroxyl groups on the acrylamide molecule. Applications Areas: The applications of AEROTEX NMA 48% range from adhesives and binders in papermaking, textiles, and non-wovens to a variety of surface coatings and resins for varnishes, films and sizing agents. Uses of AEROTEX NMA 48%: Starch modifier; reactive comonomer for vinyl acetate, SB resins. AEROTEX NMA 48% is used coating auxiliary agents, electronics chemicals, leather auxiliary agents, petroleum additives, plastic auxiliary agents, rubber auxiliary agents, surfactants, textile auxiliary agents AEROTEX NMA 48% is used in formulation or re-packing, at industrial sites and in manufacturing. AEROTEX NMA 48% is used in the following products: polymers. AEROTEX NMA 48% has an industrial use resulting in manufacture of another substance (use of intermediates). AEROTEX NMA 48% is used in the following areas: agriculture, forestry and fishing and formulation of mixtures and/or re-packaging. AEROTEX NMA 48% is used for the manufacture of: chemicals and textile, leather or fur. Release to the environment of AEROTEX NMA 48% can occur from industrial use: as an intermediate step in further manufacturing of another substance (use of intermediates), for thermoplastic manufacture and as processing aid. Release to the environment of AEROTEX NMA 48% can occur from industrial use: manufacturing of the substance. AEROTEX NMA 48% is used Chemical intermediate, reactive comonomer; production of polymers for coatings, varnishes, and adhesion; crease resistance in cotton material. AEROTEX NMA 48% has been used as a fluorescence probe for fatty acids in polyvinyl compounds, and as an electrochemical impedance spectroscopy (EIS) substrate. AEROTEX NMA 48% also reacts with acrylamide to form polymers. This reaction is catalyzed by hydroxyl groups on the acrylamide molecule. The polymerization process is reversible, with the formation of monomers and dimers. The phase transition temperature ranges from -5°C to +35°C. Chemical stability increases with increased molecular weight, but decreases when exposed to light or air. Handling and Storage of AEROTEX NMA 48%: Precautions for safe handling: Advice on safe handling: Work under hood. Hygiene measures: Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. Conditions for safe storage, including any incompatibilities: Storage conditions: Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. AEROTEX NMA 48% is highly reactive, thus, it is essential that precautions be taken to maintain stability during shipping and storage. The stability of the solution is dependent mainly upon oxygen level, contaminants, storage temperature, and pH. AEROTEX NMA 48% has a shelf life of 270 days from the date of manufacture and should be stored in a cool place where the temperature range is between 0°C and 29°C. The expiration date may be extended and COA updated after QC testing of retained samples, only for material in allnex possession. Storage class: Storage class (TRGS 510): 6.1D: Non-combustible Stability and Reactivity of AEROTEX NMA 48%: Reactivity: No data available Reactivity Profile: AEROTEX NMA 48% may be sensitive to prolonged exposure to light. Polymerization and generation of heat and flames may occur on exposure to to heat or contaminants. Incompatible with strong oxidizers. Chemical stability: The product is chemically stable under standard ambient conditions (room temperature). Contains the following stabilizer(s): Hydroquinone monomethyl ether (30 ppm) Conditions to avoid: No information available First Aid Measures of AEROTEX NMA 48%: General advice: Show this material safety data sheet to the doctor in attendance. If inhaled: After inhalation: Fresh air. Call in physician. In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. In case of eye contact: After eye contact: Rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed: Give water to drink (two glasses at most). Seek medical advice immediately. Indication of any immediate medical attention and special treatment needed: No data available Fire Fighting Measures of AEROTEX NMA 48%: Extinguishing media: Suitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media: For this substance/mixture no limitations of extinguishing agents are given. Further information: Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. Exposure Controls/Personal Protection of AEROTEX NMA 48%: Personal protective equipment: Eye/face protection: Use equipment for eye protection. Safety glasses Body Protection: protective clothing Respiratory protection: Recommended Filter type: Filter type ABEK Control of environmental exposure: Do not let product enter drains. Accidental Release Measures of AEROTEX NMA 48%: Environmental precautions: Do not let product enter drains. Methods and materials for containment and cleaning up: Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions. Take up carefully with liquid-absorbent material. Dispose of properly. Clean up affected area. Identifiers of AEROTEX NMA 48%: Molecular Weight: 101.10400 Exact Mass: 101.10 EC Number: 213-103-2 UNII: W8W68JL80Q ICSC Number: 1637 NSC Number: 553 DSSTox ID: DTXSID3020885 HScode: 2924199090 PSA: 49.33000 XLogP3: -0.37070 Density: 1.074 Melting Point: 74.5 °C Boiling Point: 318.1ºC at 760mmHg Flash Point: 146.2ºC Refractive Index: n20/D 1.413 Properties of AEROTEX NMA 48%: CBNumber: CB3182194 Molecular Formula: C4H7NO2 Molecular Weight: 101.1 MDL Number: MFCD00004597 MOL File: 924-42-5.mol Melting point: 74-75°C Boiling point: 277°C(lit.) Density: 1.082 g/mL at 20 °C vapor pressure: 31 hPa (25 °C) refractive index: n20/D 1.413 Flash point: 100°C storage temp.: Store at <= 20°C. solubility: Chloroform (Slightly), Methanol (Slightly) pka: 13.25±0.10(Predicted) form: Solid color: White to Off-White Specific Gravity: 1.074 PH: 6.0-7.0 (H2O, 20°C) Water Solubility: BRN: 506646 Stability: Light Sensitive, Moisture Sensitive InChIKey: CNCOEDDPFOAUMB-UHFFFAOYSA-N LogP: -1.81 at 20℃ and pH7 Indirect Additives used in Food Contact Substances: N-METHYLOLACRYLAMIDE FDA 21 CFR: 175.105; 176.180; 177.1010 CAS DataBase Reference: 924-42-5(CAS DataBase Reference) EWG's Food Scores: 1 FDA UNII: W8W68JL80Q Proposition 65 Lis: n-Methylolacrylamide NIST Chemistry Reference: 2-Propenamide, n-(hydroxymethyl)-(924-42-5) EPA Substance Registry System: N-Methylolacrylamide (924-42-5) Molecular Weight: 101.10 g/mol XLogP3-AA: -0.5 Hydrogen Bond Donor Count: 2 Hydrogen Bond Acceptor Count: 2 Rotatable Bond Count: 2 Exact Mass: 101.047678466 g/mol Monoisotopic Mass: 101.047678466 g/mol Topological Polar Surface Area: 49.3Ų Heavy Atom Count: 7 Complexity: 79.8 Isotope Atom Count: 0 Defined Atom Stereocenter Count: 0 Undefined Atom Stereocenter Count: 0 Defined Bond Stereocenter Count: 0 Undefined Bond Stereocenter Count: 0 Covalently-Bonded Unit Count: 1 Compound Is Canonicalized: Yes Water Solubility: Solubility in water, g/100ml at 20°C: 188 Storage Conditions: Refrigerator Vapor Pressure: Vapour pressure, Pa at 25°C: 0.03 (negligible) Air and Water Reactions: Soluble in water. Reactive Group: Alcohols and Polyols Reactivity Alerts: Polymerizable Chemical Name: N-(Hydroxymethyl)acrylamide CAS Number: 924-42-5 Molecular Formula: C₄H₇NO₂ Appearance: White to Off-White Solid Melting Point: 74-76°C Molecular Weight: 101.1 Storage: -20°C Solubility: Chloroform (Slightly), Methanol (Slightly) Stability: Light Sensitive, Moisture Sensitive Physical state: liquid Color: colorless, yellow Odor: formaldehyde-like Melting point/freezing point: Melting point/range: -10 °C Initial boiling point and boiling range: No data available Flammability (solid, gas): No data available Upper/lower flammability or explosive limits: No data available Flash point: > 93 °C – closed cup
Autoignition temperature: Not applicable
Decomposition temperature: No data available
pH: 6,0 – 7,0
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility at 20 °C soluble
Partition coefficient n-octanol/water: No data available
Vapor pressure 31,68 hPa at 25 °C
Density 1,074 g/cm3 at 25 °C
Relative density No data available
Relative vapor density: No data available
Particle characteristics: No data available
Explosive properties: Not classified as explosive.
Oxidizing properties: none
Other safety information: No data available
Density: 1.074
Boiling Point: 318.1±34.0 °C at 760 mmHg
Melting Point: 74-75°C
Molecular Formula: C4H7NO2
Molecular Weight: 101.104
Flash Point: 146.2±25.7 °C
Exact Mass: 101.047676
PSA: 49.33000
LogP: -1.48
Vapour Pressure: 0.0±1.5 mmHg at 25°C
Index of Refraction: 1.459
Storage condition: Refrigerator
Water Solubility: Melting Point: 76°C
Color: White
UN Number: 3531
Formula Weight: 101.11
Percent Purity: ≥98.0% (T)
Physical Form: Crystalline Powder
Chemical Name or Material: N-(Hydroxymethyl)acrylamide
Appearance: Clear to slightly hazy liquid
Color: Yellow to pink
Color, APHA: ≤ 40
Total solids, % by weight: 46 – 50
Free formaldehyde, % by weight: ≤ 0.25
Copper in solution, ppm: ≤ 2.5
MEHQ inhibitor, ppm: 30 ± 5
pH: 5.5 – 7.0
Specific Gravity at 25°C: 1.05 g/ml