POLYISOBUTENE
POLYISOBUTENE
Polyisobutene is known for its excellent flexibility and durability, with high resistance to heat, chemicals, and weathering, making it suitable for a wide range of applications.
Polyisobutene is commonly used as a sealant in construction and automotive industries, as well as in the formulation of adhesives, lubricants, and fuel additives.
In the cosmetics industry, polyisobutene is valued for its film-forming and adhesive properties, providing a smooth texture and enhanced moisture retention in products like lip glosses and skin creams.
CAS Number: 9003-27-4
EC Number: 204-066-3
Chemical Formula: (C4H8)n
Molecular Weight:56.10632
Synonyms: Poly(isobutylene), PIB, Isobutylene Polymer, Isobutene Polymer, Butyl Rubber, Butyl Elastomer, Butyl Isoprene Rubber, Polyisobutylenes, Poly(isobutene), Isobutylene-Isoprene Copolymer, Polyisobutylene (PIB), Isobutene-Isoprene Copolymer, Polybutene, Butene Polymer, 2-methylpropene Polymer, Butylene Polymer, Poly(isobutylene) rubber, Polyisobutylene Rubber, Polyisobutylene Resin, Isobutylene-Isoprene Rubber, Polyisobutylene Liquid, Polybutylene, Butyl Polymer, Butyl Resin, Butyl Adhesive, Butyl Sealant, Polyisobutene Emulsion, Isobutene-Isoprene Resin, Poly(isobutylene) Emulsion, Isobutylene-Isoprene Resin, Butyl Seal, Polyisobutylene Oil, Isobutylene-Isoprene Oil, Butyl Oil, Butyl Lubricant, Poly(isobutene) Oil, Polyisobutylene Lubricant, Isobutylene-Isoprene Lubricant, Butyl Additive, Polyisobutene Additive, Isobutylene-Isoprene Additive, Butyl Compound, Poly(isobutylene) Compound, Isobutylene-Isoprene Compound, Polyisobutylene Adhesive, Poly(isobutene) Adhesive, Isobutylene-Isoprene Adhesive
Polyisobutene is a synthetic polymer derived from the monomer isobutylene.
Polyisobutene is a type of elastomer or synthetic rubber that has a wide range of applications across various industries.
Polyisobutene is a synthetic polymer derived from the monomer isobutylene.
Polyisobutene is a type of elastomer or synthetic rubber that has a wide range of applications across various industries.
Polyisobutene is known for its flexibility, durability, and resistance to heat, chemicals, and weathering, making it suitable for numerous purposes.
Polyisobutene is a versatile synthetic polymer with a wide range of applications.
Polyisobutene is known for its excellent flexibility and durability.
Polyisobutene exhibits high resistance to heat, chemicals, and weathering.
Polyisobutene is commonly used as a sealant due to its ability to form strong bonds with various surfaces.
Polyisobutene is often employed in adhesive formulations for its adhesive properties.
Polyisobutene can act as a lubricant, reducing friction between moving parts.
Polyisobutene is utilized in the production of butyl rubber, which is valued for its impermeability to gases.
Polyisobutene is often found in automotive applications, such as tire inner liners and gaskets.
Polyisobutene is used in the construction industry for sealing and waterproofing purposes.
Polyisobutene serves as a key ingredient in the manufacture of chewing gum for its elasticity and chewiness.
Polyisobutene is employed in the production of transdermal patches for drug delivery.
Polyisobutene is used in the formulation of cosmetic and personal care products, such as lipsticks and lip balms.
Polyisobutene can be found in medical applications, including adhesive bandages and wound dressings.
Polyisobutene is utilized in the production of fuel additives to improve fuel efficiency and reduce emissions.
Polyisobutene is valued for its low gas permeability, making it suitable for packaging materials.
Polyisobutene is used in the production of synthetic lubricants for machinery and equipment.
Polyisobutene is employed in the production of electrical insulation materials due to its dielectric properties.
Polyisobutene can be found in the formulation of food-grade lubricants for machinery in the food industry.
Polyisobutene is used in the production of ink and printing toners for its adhesive properties.
Polyisobutene serves as a binder in the formulation of paints and coatings for improved durability.
Polyisobutene is utilized in the production of chewing gum base for its elasticity and texture.
Polyisobutene is employed in the formulation of hydraulic fluids for its lubricating
Polyisobutene is used in the production of synthetic rubber products, such as conveyor belts and hoses.
Polyisobutene is employed in the formulation of pharmaceutical products for controlled release applications.
Overall, Polyisobutene is a versatile polymer with diverse applications across industries due to its unique combination of properties.
Polyisobutene is not a naturally occurring substance.
Polyisobutene is a synthetic polymer, which means it is artificially produced rather than being found in nature.
Polyisobutene is typically created through the process of polymerization using isobutylene, a hydrocarbon derived from petroleum or natural gas feedstocks.
Hydrogenated Polyisobutene And Polyisobutylene:
Hydrogenated Polyisobutene is a compound created via hydrogenation.
Hydrogenation refers to a reaction where hydrogen alters the properties of a select substance.
Polyisobutene, in its non-hydrogenated form, is a synthetic polymer; it’s a liquid with film-forming and adhesive properties that make it valuable in cosmetics.
In the cosmetics industry, hydrogenated Polyisobutene is a popular ingredient because of the emollient and a thickening properties Polyisobutene can impart in skincare products and makeup, including, popularly, lip glosses.
The use of hydrogenated Polyisobutene in lip gloss is so popular because it lends a smooth and glossy texture, increases shine, and provides hydrating properties, all desirable when it comes to lip glosses.
One of the perks of hydrogenated Polyisobutene in cosmetics is its impressive ability to prevent water loss from the skin, meaning it helps ‘lock in’ moisture, keeping skin (or lips) soft.
Another perk is the fact that hydrogenated Polyisobutene has a non-greasy texture and a non-sticky feel, and many people prefer makeup, especially glosses, to be just that: non-sticky in feel and non-greasy in texture and feel.
First of all, Polyisobutene can negatively affect those who are sensitive or allergic to it, leading to skin irritation or adverse reactions.
Natural alternatives are often preferred among those seeking to eliminate toxins and lead their healthiest lifestyle, so the strong ‘synthetic’ factor to Polyisobutene is off-putting.
Natural options to replace hydrogenated Polyisobutene might include plant-based oils and waxes, such as but not limited to organic jojoba oil, almond oil, coconut oil, and shea butter.
These nature-provided alternatives offer similar moisturizing and protective properties while being derived from sustainable sources that organic ingredient-loving aficionados approve.
Hydrogenated Polyisobutene might come with some notable performance advantages when used in cosmetics—especially lip glosses.
Applications
Polyisobutene is commonly used as a sealant in construction and automotive industries.
Polyisobutene is employed as an adhesive in various applications, including packaging and manufacturing.
Polyisobutene serves as a key ingredient in the production of butyl rubber for tire manufacturing.
Polyisobutene is utilized in the formulation of chewing gum for its elasticity and texture.
Polyisobutene is used in the production of transdermal patches for drug delivery applications.
Polyisobutene is employed as a binder in the formulation of paints and coatings.
This polymer is used in the production of adhesives for labels and tapes.
Polyisobutene serves as a lubricant additive in automotive and industrial lubricants.
Polyisobutene is utilized in the formulation of hydraulic fluids for machinery and equipment.
Polyisobutene is employed in the production of electrical insulation materials.
Polyisobutene is used as a fuel additive to improve fuel efficiency and reduce emissions.
Polyisobutene is utilized in the formulation of cosmetic and personal care products, such as lipsticks and mascaras.
Polyisobutene serves as a key ingredient in the production of food-grade lubricants for machinery in the food industry.
Polyisobutene is used in the formulation of pharmaceutical products for controlled release applications.
Polyisobutene is employed in the production of synthetic lubricants for machinery and equipment.
Polyisobutene serves as a binder in the formulation of ink and printing toners.
Polyisobutene is utilized in the production of synthetic rubber products, such as conveyor belts and hoses.
Polyisobutene is employed in the formulation of adhesive bandages and wound dressings for medical applications.
Polyisobutene is used in the production of synthetic fibers for textiles and clothing.
Polyisobutene serves as a key ingredient in the formulation of industrial coatings for corrosion protection.
Polyisobutene is employed in the production of packaging materials, such as films and wraps.
Polyisobutene is utilized in the formulation of chewing gum base for its elasticity and texture.
Polyisobutene serves as a sealant in the construction of buildings and structures.
Polyisobutene is employed as a binding agent in the formulation of pharmaceutical tablets and capsules.
Overall, Polyisobutene finds applications across a wide range of industries due to its versatility and unique properties.
Polyisobutene is utilized in the production of fuel system components such as fuel hoses and seals in automobiles and aircraft.
Polyisobutene is used as a component in the formulation of lubricating greases for various industrial and automotive applications.
Polyisobutene serves as a thickening agent in the formulation of greases and pastes for lubricating and sealing applications.
Polyisobutene is employed in the production of damping materials used in automotive suspension systems to reduce noise and vibrations.
Polyisobutene is utilized in the manufacture of pressure-sensitive adhesives for tapes, labels, and stickers.
Polyisobutene serves as a processing aid in the production of plastics and elastomers to improve flow properties and processing conditions.
Polyisobutene is employed in the formulation of anti-foaming agents used in industrial processes such as oil refining and wastewater treatment.
Polyisobutene is used as a component in the formulation of anti-corrosion coatings for metal surfaces in marine and industrial applications.
Polyisobutene serves as a base material for the production of synthetic rubber compounds used in the manufacture of tires, conveyor belts, and industrial hoses.
Polyisobutene is utilized in the production of vibration-damping materials used in automotive and aerospace applications.
Polyisobutene is employed in the formulation of encapsulants and potting compounds used in electronic and electrical applications.
Polyisobutene is used as a viscosity modifier in the formulation of hydraulic fluids and transmission fluids for automotive and industrial equipment.
Polyisobutene serves as a base material for the production of high-performance elastomeric seals and gaskets used in automotive, aerospace, and industrial applications.
Polyisobutene is utilized in the formulation of mold release agents used in plastic and rubber molding processes.
Polyisobutene is employed in the production of damping materials used in the construction of buildings and infrastructure to reduce noise and vibrations.
Polyisobutene serves as a component in the formulation of anti-blocking agents used in plastic films and coatings to prevent sticking and blocking during storage and handling.
Polyisobutene is used in the production of insulation materials for thermal and acoustic insulation applications in buildings and appliances.
Polyisobutene is employed as a processing aid in the production of rubber compounds to improve mixing and dispersion of fillers and additives.
Polyisobutene serves as a base material for the production of butyl-based adhesives and sealants used in automotive, construction, and industrial applications.
Polyisobutene is utilized in the formulation of waterproofing membranes and coatings used in roofing and construction applications.
Polyisobutene is employed in the production of anti-fogging agents used in automotive and marine windshields and mirrors.
Polyisobutene serves as a component in the formulation of foam stabilizers used in the production of polyurethane and polystyrene foam products.
Polyisobutene is used in the formulation of anti-stick coatings used in cookware, bakeware, and food processing equipment.
Polyisobutene is employed in the production of surfactants and emulsifiers used in the formulation of detergents, personal care products, and industrial cleaners.
Overall, Polyisobutene is a versatile polymer with a wide range of applications across industries, contributing to the performance, durability, and functionality of various products and materials.
Uses of Polyisobutene:
Polyisobutene is used as a binder, film-former, and non-aqueous viscosity increasing agent in cosmetic products.
As a binding agent, Polyisobutene helps in binding or holding together the ingredients in a cosmetic product in the compressed cake or tablet form of product, for example, a compressed powder or eye shadow.
Polyisobutene works as a non-reactive binder, which is a very important characteristic of a binder.
As a film-forming agent when applied on the hair or skin, Polyisobutene forms a supple, cohesive, and continuous layer.
This layer/film has water-binding properties that leave a silky and smooth effect on the skin.
Polyisobutene also functions as a viscosity increasing agent which when used increases the thickness of the solution and that gives ideal or acceptable viscosity to the product that is just right for use. Polyisobutene is well tolerated by the skin or quite mild on the skin.
Polyisobutene is used in formulations of make-up products, hair care, and skincare products.
Polyisobutene is an effective ingredient that finds many uses in the cosmetic and skin care industry.
Skin care:
Polyisobutene serves as an emollient and moisturizer.
Polyisobutene forms a protective barrier on the skin’s surface, preventing transepidermal water loss and helping to retain moisture.
This makes Polyisobutene a valuable ingredient in body lotions and moisturizers, providing long-lasting hydration and smoothness to the skin
Cosmetic products:
Polyisobutene is utilized for its film-forming properties.
Polyisobutene imparts a smooth and silky texture to products, allowing for easy application and enhancing their overall performance.
In lipsticks and lip glosses, Polyisobutene helps to create a long-lasting, non-sticky, and shiny finish
Common Uses:
Adhesives:
Polyisobutene is used in the production of pressure-sensitive adhesives, which are found in products like tapes, labels, and sticky notes.
Sealants:
Polyisobutene is used in sealants for applications like construction, automotive, and aerospace, where a flexible and long-lasting seal is required.
Lubricants:
Polyisobutene can be found in the formulation of lubricating oils and greases, as it provides good viscosity control and stability.
Tires:
In the rubber industry, Polyisobutene is used as a component in tire manufacturing, contributing to improved fuel efficiency and tread wear.
Pharmaceutical and cosmetic products:
Polyisobutene is used in various personal care and pharmaceutical products, such as lip balms, ointments, and creams, for its emollient and protective properties.
Fuel and oil additives:
Polyisobutene is sometimes used as an additive to improve the performance and stability of fuels and lubricants.
Polyisobutene is typically produced through the polymerization of isobutene, a gaseous hydrocarbon, under controlled conditions.
The resulting polymer can have various molecular weights and properties depending on the specific manufacturing process and intended application.
Polyisobutene’s versatility and beneficial characteristics have made Polyisobutene a valuable material in many industries.
Benefits of Polyisobutene:
Polyisobutene offers several benefits in various applications due to its unique properties:
Impermeability:
Polyisobutene is highly impermeable to gases and moisture, making it effective for creating seals and barriers in products like adhesives, sealants, and tires.
Elasticity:
Polyisobutene has elastic properties, allowing it to stretch and return to its original shape.
This flexibility is valuable in applications like sealants, where a pliable and long-lasting seal is needed.
Adhesion:
Polyisobutene is often used in pressure-sensitive adhesives, providing strong adhesion to various surfaces, such as in adhesive tapes and labels.
Lubrication:
Polyisobutene is used in the formulation of lubricants and greases, contributing to viscosity control and stability in machinery and automotive applications.
Fuel Efficiency:
In the tire industry, Polyisobutene can improve fuel efficiency and tread wear when used as a component in tire manufacturing.
Personal Care:
Polyisobutene is found in cosmetics and pharmaceutical products, like lip balms and ointments, for its emollient properties that help moisturize and protect the skin.
Stability:
Polyisobutene can enhance the stability and performance of fuels and lubricants when used as an additive.
Versatility:
Polyisobutene’s versatility in terms of molecular weight and properties allows for customization to suit specific applications.
Overall, the benefits of Polyisobutene lie in its ability to provide impermeability, flexibility, and adhesion, making it a valuable material in numerous industries and products.
Key Benefits of Polyisobutene of Using The Connect PB Range:
Very tacky liquid polymer, non-hazardous and no-odor
Superior corrosion and oxidation-stability against heat, reagent and UV ray
High thickening efficiency with excellent viscosity-index
Completely hydrophobic with extremely low electrical conductivity
Superior solubility to kerosene, coal tar, aromatic compound, hydrogen carbonate chloride, lubricant
Permanent non-drying properties
Easy to store with no evaporation or solidification.
Functions of Polyisobutene In Cosmetic Products:
Binding:
Polyisobutene ensures the cohesion of powdered products
Film Forming:
Polyisobutene produces a continuous film on skin, hair and / or nails
Viscosity Controlling:
Polyisobutene increases or decreases the viscosity of cosmetic products
Scientific Facts of Polyisobutene:
Polyisobutene is often referred to as butyl rubber and is produced in a wide range of molecular weights; the lower molecular weight Polyisobutenes are very viscous, soft, and tacky semi-liquids while the higher molecular weight Polyisobutenes are tough and elastic rubbery solids.
Hydrogenated Polyisobutene is also produced in a wide range of molecular weights and is widely used as a substitute for another cosmetic ingredient, squalene.
Chemical Properties of Polyisobutene:
Polyisobutene is composed of long-chain hydrocarbon formed by polymerization of isobutene, and is extremely stable under normal conditions.
Polyisobutene is transparent non-noxious high-consistency semi-solid polymer free of impurities.
The physical properties of Polyisobutene are very dependent on molecular weight.
Polymers with average molecular weight (Mw) of about 15 000 are sticky viscous liquids whilst those with molecular weight of 100000-200000 are rubber-like, resembling unmilled crepe rubber.
Polyisobutene is non-crystalline when unstretched and is therefore soluble at room temperature in hydrocarbons and halogenated hydrocarbons.
Polyisobutene is resistant to most acids, alkalis and aqueous solutions, as would be expected from its saturated hydrocarbon structure and absence of tertiary hydrogen atoms.
The lack of tertiary hydrogen atoms renders Polyisobutene more resistant to oxidation than polypropylene; also, the less numerous and partially shielded methylene groups in polyisobutene are less reactive than those in polyethylene.
However, Polyisobutene is rather susceptible to thermal degradation since chain scission is favoured by the greater stability of the resultant tertiary free radical:
free radical of Polyisobutene may be chlorinated but the reaction is accompanied by severe degradation.
A limitation of Polyisobutene is its tendency to cold flow and, as a result, the polymer finds little use in self-supporting form. Applications of Polyisobutene are restricted mainly to adhesives, fabric and paper coatings, and blends with other polymers.
Low molecular weight Polyisobutene is also used in caulking compounds.
Skin Sensitivities of Polyisobutene:
While Polyisobutene is generally well-tolerated, individual skin sensitivities can vary.
If you notice adverse reactions or skin irritations after using a product containing Polyisobutene, it’s advisable to discontinue use and consult with a healthcare professional.
In a nutshell, Polyisobutene can be safe when used in consumer products, but the safety can be influenced by factors such as sourcing, purity, and manufacturing practices.
Consumers should choose products from reputable brands and be aware of any sensitivities they may have to specific ingredients.
Additionally, adhering to product usage guidelines and discontinuing use in case of adverse reactions is important.
If you have specific concerns about a product or ingredient, consult with a healthcare professional or dermatologist for personalized guidance.
Sourcing of Polyisobutene:
The quality and safety of Polyisobutene can be influenced by its source.
Polyisobutene used in consumer products should be sourced from reputable suppliers who adhere to quality and safety standards.
Purity of Polyisobutene:
The purity of Polyisobutene is essential.
Impurities in Polyisobutene can potentially pose risks.
High-quality Polyisobutene used in consumer products should undergo rigorous purification processes to remove impurities.
Manufacturing Concerns of Polyisobutene:
The safety of products containing Polyisobutene also depends on the overall formulation and manufacturing processes.
Products should be manufactured following good manufacturing practices (GMP) to ensure quality and safety.
Preparation of Polyisobutene:
Silicone rubbers are prepared as follows:
Preparation of Silicone rubbers.
Other groups may replace the methyl groups.
Silicone rubbers have excellent ozone and weathering resistance, good electrical properties, and good adhesion to metal.
Alternatives of Polyisobutene:
SQUALANE,
CAPRYLIC CAPRIC TRIGLYCERIDE,
SYNTHETIC JOJOBA OIL
Handling and Storage of Polyisobutene:
Handling:
Avoid Skin and Eye Contact:
Wear appropriate protective equipment to prevent skin and eye contact.
Use in Well-Ventilated Areas:
Ensure good ventilation to minimize inhalation exposure.
Avoid Ingestion and Inhalation:
Keep away from food and drink.
Avoid breathing in vapors or mists.
Storage:
Store in a Cool, Dry Place:
Keep away from heat, sparks, and open flames.
Keep Containers Tightly Closed:
Prevent moisture and contaminants from entering the container.
Use Proper Containers:
Store in suitable containers that are compatible with polyisobutene.
Stability and Reactivity of Polyisobutene:
Chemical Stability:
Polyisobutene is generally stable under normal conditions of use and storage.
Reactivity:
Incompatible Materials:
Avoid contact with strong oxidizers and acids.
Conditions to Avoid:
Keep away from high temperatures and open flames.
Hazardous Decomposition Products:
Combustion:
May produce carbon monoxide, carbon dioxide, and other toxic fumes.
Safety Profile of Polyisobutene:
Polyisobutene is generally regarded as safe for cosmetic use, posing minimal risk of skin irritations or allergies.
Polyisobutene is non-comedogenic, meaning it does not clog pores or promote acne formation.
Moreover, Polyisobutene is derived from petroleum or plant-based sources, making it suitable for vegan-friendly cosmetic formulations.
First Aid Measures of Polyisobutene:
Inhalation:
Move the person to fresh air.
Seek medical attention if symptoms persist.
Skin Contact:
Wash affected skin with soap and water.
Remove contaminated clothing.
Seek medical attention if irritation occurs.
Eye Contact:
Rinse eyes with water for at least 15 minutes.
Seek medical attention immediately.
Ingestion:
Do not induce vomiting.
Rinse mouth with water.
Seek medical attention.
Fire Fighting Measures of Polyisobutene:
Suitable Extinguishing Media:
Use foam, dry chemical, or carbon dioxide (CO2).
Water may be ineffective.
Specific Hazards:
Combustion may produce toxic fumes.
Wear self-contained breathing apparatus (SCBA) and full protective clothing.
Special Procedures:
Move containers from fire area if Polyisobutene can be done without risk.
Cool containers with water spray.
Accidental Release Measures of Polyisobutene:
Personal Precautions:
Wear protective equipment.
Avoid breathing vapors and contact with skin and eyes.
Environmental Precautions:
Prevent entry into drains, sewers, and watercourses.
Contain spills with dikes or barriers.
Clean-Up Procedures:
Absorb spills with inert materials (e.g., sand, earth).
Dispose of in accordance with local regulations.
Clean contaminated surfaces thoroughly.
Exposure Controls/Personal Protective Equipment of Polyisobutene:
Exposure Limits:
Ensure exposure levels are below occupational exposure limits.
Consult material safety data sheets (MSDS) or safety data sheets (SDS) for specific information.
Engineering Controls:
Provide adequate ventilation or use local exhaust systems to reduce inhalation risk.
Personal Protective Equipment:
Respiratory Protection:
Use a respirator if ventilation is inadequate or if exposure limits are exceeded.
Skin Protection:
Wear protective gloves and clothing to avoid skin contact.
Eye Protection:
Use safety glasses or goggles to prevent eye exposure.
Identifiers of Polyisobutene:
CAS Number: 9003-27-4
EC Number: 204-066-3
MDL Number: MFCD00084436
Chem/IUPAC Name: Homopolymer of 2-methyl-1 propene
Linear Formula: [CH2C(CH3)2]n
Chemical formula: (C4H8)n
Properties of Polyisobutene:
Chemical formula: (C4H8)n
Molar mass: Variable
Boiling Point: 300°C
Melting Point: 54-56°C
Solubility: Insoluble in water
Viscosity: High
CBNumber:CB8147859
Molecular Formula:C4H8
Molecular Weight:56.10632
MDL Number:MFCD00084436
MOL File:9003-27-4.mol
Melting point: 54-56 °C
Boiling point: 300 °C
Density: 0.92 g/mL at 25 °C (lit.)
refractive index: n20/D 1.51
form: slab/chunk
Stability: Stability
InChI: InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3
InChIKey: VQTUBCCKSQIDNK-UHFFFAOYSA-N
SMILES: C=C(C)C
Substances Added to Food (formerly EAFUS): POLYISOBUTYLENE (MIN M W 37,000)
FDA 21 CFR: 172.615; 175.125; 175.300
EWG’s Food Scores: 1
Melting Point N/A
Boiling Point N/A
Flash Point N/A
Molecular Formula C4H8
Molecular Weight 56.10630
Density 0.92 g/mL at 25 °C(lit.)
